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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union

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https://doi.org/10.5194/amt-2017-341
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
Research article
21 Sep 2017
Review status
This discussion paper is a preprint. It is a manuscript under review for the journal Atmospheric Measurement Techniques (AMT).
Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research
Adam W. Birdsall1, Ulrich K. Krieger2, and Frank N. Keutsch1,3 1Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
2Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
3School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA
Abstract. New analytical techniques are needed to improve our understanding of the intertwined physical and chemical processes that affect the composition of aerosol particles in the Earth’s atmosphere, such as gas–particle partitioning and homogenous or heterogeneous chemistry, and their ultimate relation to air quality and climate. We describe a new laboratory setup that couples an electrodynamic balance (EDB) to a mass spectrometer (MS). The EDB stores a single laboratory-generated particle in an electric field under atmospheric conditions for an arbitrarily long length of time. The particle is then transferred via gas flow to an ionization region that vaporizes and ionizes the analyte molecules before MS measurement. We demonstrate the feasibility of the technique by tracking evaporation of polyethylene glycol molecules and finding agreement with a kinetic model. Fitting data to the kinetic model also allows determination of vapor pressures to within a factor of 2. This EDB-MS system can be used to study fundamental chemical and physical processes involving particles that are difficult to isolate and study with other techniques. The results of such measurements can be used to improve our understanding of atmospheric particles.

Citation: Birdsall, A. W., Krieger, U. K., and Keutsch, F. N.: Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research, Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2017-341, in review, 2017.
Adam W. Birdsall et al.
Adam W. Birdsall et al.
Adam W. Birdsall et al.

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Short summary
We have developed a laboratory system that provides mass spectra of individual particles, roughly 20 microns in diameter, after they have been levitated in an electric field. Measured evaporation of polyethylene glycol particles was found to agree with a kinetic model. The system can be used to study fundamental chemical and physical processes involving particles that are difficult to isolate and study with other techniques, and hence improve our understanding of atmospheric particles.
We have developed a laboratory system that provides mass spectra of individual particles,...
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