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Atmospheric Measurement Techniques An interactive open-access journal of the European Geosciences Union

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https://doi.org/10.5194/amt-2017-213
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 4.0 License.
Research article
28 Jul 2017
Review status
This discussion paper is a preprint. A revision of this manuscript was accepted for the journal Atmospheric Measurement Techniques (AMT) and is expected to appear here in due course.
A technique for the measurement of organic aerosol hygroscopicity, oxidation level, and volatility distributions
Kerrigan P. Cain1 and Spyros N. Pandis1,2,3 1Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, USA
2Institute of Chemical Engineering Sciences, ICE-HT, Patras, Greece
3Department of Chemical Engineering, University of Patras, Patras, Greece
Abstract. Hygroscopicity, oxidation level, and volatility of organic pollutants are three crucial properties that determine their fate in the atmosphere. This study assesses the feasibility of a novel measurement and analysis technique to determine these properties of organic aerosol components at the same time and to establish their relationship. The proposed experimental setup utilizes a cloud condensation nuclei counter to quantify hygroscopic activity, an aerosol mass spectrometer to measure the oxidation level, and a thermodenuder to evaluate the volatility. The setup was first tested with secondary organic aerosol (SOA) formed from the ozonolysis of α-pinene. The results of the first experiments indicated that, for this system, the less volatile SOA contained species that had on average lower O : C ratios and hygroscopicities. In this SOA system, both low and high volatility components can have comparable oxidation levels and hygroscopicities. The method developed here can be used to provide valuable insights about the relationships among organic aerosol hygroscopicity, oxidation level, and volatility.

Citation: Cain, K. P. and Pandis, S. N.: A technique for the measurement of organic aerosol hygroscopicity, oxidation level, and volatility distributions, Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2017-213, in review, 2017.
Kerrigan P. Cain and Spyros N. Pandis
Kerrigan P. Cain and Spyros N. Pandis

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Short summary
Hygroscopicity, oxidation level, and volatility of organic pollutants are three crucial 10 properties that determine their fate in the atmosphere. This study assesses the feasibility of a novel measurement and analysis technique to determine these properties of organic aerosol components at the same time and to establish their relationship.
Hygroscopicity, oxidation level, and volatility of organic pollutants are three crucial 10...
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