Atmospheric Measurement Techniques Discussions www.atmos-meas-tech-discuss.net 1867-8610 3 2 2010 10.5194/amtd-3-965-2010 http://www.atmos-meas-tech-discuss.net/3/965/2010/ http://www.atmos-meas-tech-discuss.net/3/965/2010/amtd-3-965-2010.html http://www.atmos-meas-tech-discuss.net/3/965/2010/amtd-3-965-2010.pdf 965 988 2010-03-15 Formaldehyde measurements by Proton Transfer Reaction – Mass Spectrometry (PTR-MS): correction for humidity effects A. Vlasenko alexander.vlasenko@ec.gc.ca A. M. Macdonald S. J. Sjostedt J. P. D. Abbatt Department of Chemistry, University of Toronto, Toronto, Canada Science and Technology Branch, Environment Canada, Toronto, Canada now at: Science and Technology Branch, Environment Canada, Toronto, Canada Formaldehyde measurements can provide useful information about photochemical activity in ambient air, given that HCHO is formed via numerous oxidation processes. Proton transfer reaction mass spectrometry (PTR-MS) is an online technique that allows measurement of VOCs at the sub-ppbv level with good time resolution. PTR-MS quantification of HCHO is hampered by the humidity dependence of the instrument sensitivity, with higher humidity leading to loss of PTR-MS signal. In this study we present an analytical, first principles approach to correct the PTR-MS HCHO signal according to the concentration of water vapor in sampled air. The results of the correction are validated by comparison of the PTR-MS results to those from a Hantzsch fluorescence monitor which does not have the same humidity dependence. Results are presented for an intercomparison made during a field campaign in rural Ontario at Environment Canada's Centre for Atmospheric Research Experiments. Ammann, C., Spirig, C., Neftel, A., Steinbacher, M., Komenda, M., and Schaub, A.: Application of PTR-MS fro measurements of biogenic VOC in a deciduous forest, Int. J. 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