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<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques Discussions</journal_title>
		<journal_url>www.atmos-meas-tech-discuss.net</journal_url>
		<eissn>1867-8610</eissn>
		<volume_number>3</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/amtd-3-55-2010</doi>
	<article_url>http://www.atmos-meas-tech-discuss.net/3/55/2010/</article_url>
	<abstract_html>http://www.atmos-meas-tech-discuss.net/3/55/2010/amtd-3-55-2010.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech-discuss.net/3/55/2010/amtd-3-55-2010.pdf</fulltext_pdf>
	<start_page>55</start_page>
	<end_page>110</end_page>
	<publication_date>2010-01-07</publication_date>
	<article_title content_type="html">A remote sensing technique for global monitoring of power plant CO&lt;sub&gt;2&lt;/sub&gt; emissions from space and  related applications</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>H. Bovensmann</name>
		</author>
		<author numeration="2" affiliations="1">
			<name>M. Buchwitz</name>
			<email>michael.buchwitz@iup.physik.uni-bremen.de</email>
		</author>
		<author numeration="3" affiliations="1">
			<name>J. P. Burrows</name>
		</author>
		<author numeration="4" affiliations="1">
			<name>M. Reuter</name>
		</author>
		<author numeration="5" affiliations="1">
			<name>T. Krings</name>
		</author>
		<author numeration="6" affiliations="1">
			<name>K. Gerilowski</name>
		</author>
		<author numeration="7" affiliations="1">
			<name>O. Schneising</name>
		</author>
		<author numeration="8" affiliations="1">
			<name>J. Heymann</name>
		</author>
		<author numeration="9" affiliations="2">
			<name>A. Tretner</name>
		</author>
		<author numeration="10" affiliations="2">
			<name>J. Erzinger</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Institute of Environmental Physics (IUP), University of Bremen FB1, Otto Hahn Allee 1,  28334 Bremen, Germany</affiliation>
		<affiliation numeration="2" content_type="html">Helmholtz Centre Potsdam â€“ GFZ German Research Centre for Geosciences, Telegrafenberg,  14473 Potsdam, Germany</affiliation>
	</affiliations>
	<abstract content_type="html">Carbon dioxide (CO&lt;sub&gt;2&lt;/sub&gt;) is the most important anthropogenic greenhouse gas causing
      global warming.  The atmospheric CO&lt;sub&gt;2&lt;/sub&gt; concentration increased by more than 30% since
      pre-industrial times â€“ primarily due to burning of fossil fuels â€“ and still continues to
      increase. Reporting of CO&lt;sub&gt;2&lt;/sub&gt; emissions is required by the Kyoto protocol. Independent
      verification of reported emissions, which are typially not directly measured, by methods
      such as inverse modeling of measured atmospheric CO&lt;sub&gt;2&lt;/sub&gt; concentrations is currently not
      possible globally due to lack of appropriate observations.  Existing greenhouse gas
      observing satellites such as SCIAMACHY and GOSAT focus on advancing our understanding of
      natural CO&lt;sub&gt;2&lt;/sub&gt; sources and sinks.  The obvious next step for future generation
      satellites is to also measure anthropogenic CO&lt;sub&gt;2&lt;/sub&gt; emissions.  Here we present
      a promising satellite remote sensing technology based on spectroscopic measurements of
      reflected solar radiation in the short-wave infrared (SWIR) and near-infrared (NIR) spectral
      regions and show, using power plants as an example, that strong localized CO&lt;sub&gt;2&lt;/sub&gt; point
      sources can be detected and their emissions quantified.  This requires mapping the
     CO&lt;sub&gt;2&lt;/sub&gt; column distribution at a spatial resolution of 2&amp;times;2 km&lt;sup&gt;2&lt;/sup&gt; or better
      with a precision of about 0.5% (2 ppm) or better of the background column.  We
      indicate that this can be achieved with existing technology.  For a single satellite in
      sun-synchronous orbit with an across-track swath width of 500 km each power plant is
      overflown every 6 days or faster.  Based on clear sky statistics we conservatively estimate
      that about one useful measurement per 1â€“2 months for a given power plant can typically be
      achieved.  We found that the uncertainty of the retrieved power plant CO&lt;sub&gt;2&lt;/sub&gt; emission
      during a single satellite overpass is in the range 0.5â€“5 MtCO&lt;sub&gt;2&lt;/sub&gt;/year â€“ depending on
      observation conditions â€“ which is about 2â€“20% of the CO&lt;sub&gt;2&lt;/sub&gt; emission of large power
      plants (25 Mt CO&lt;sub&gt;2&lt;/sub&gt;/year). The investigated instrument aims at fulfilling all
      requirements for global regional-scale CO&lt;sub&gt;2&lt;/sub&gt; and CH&lt;sub&gt;4&lt;/sub&gt; surface flux inverse
      modeling. Using a significantly less demanding instrument concept based on a single SWIR
      channel we indicate that this also enables the monitoring of power plant CO&lt;sub&gt;2&lt;/sub&gt;
      emissions in addition to high-quality methane retrievals. The latter has already been
      demonstrated by SCIAMACHY. The discussed technology has the potential to significantly
      contribute to an independent verification of reported anthropogenic CO&lt;sub&gt;2&lt;/sub&gt; emissions
      and therefore could be an important component of a future global anthropogenic CO&lt;sub&gt;2&lt;/sub&gt;
      emission monitoring system. This is of relevance in the context of Kyoto protocol follow-on
      agreements but also allows to detect and monitor strong natural CO&lt;sub&gt;2&lt;/sub&gt; and CH&lt;sub&gt;4&lt;/sub&gt;
      emitters such as (mud) volcanoes.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Ackerman,~S., Strabala,~K., Menzel,~W., Frey,~R., Coeller,~C., and Gumley,~L.: Discriminating clear sky from clouds with MODIS,~J. Geophys. Res., 103, 32141â€“32157, 1998. </reference>
		<reference numeration="2" content_type="text"> Ackerman,~S A., Holz,~R E., Frey,~R., Eloranta,~E W., Maddux,~B C., and McGill,~M.: Cloud detection with MODIS. Part II: validation, J. Atmos. Ocean. Tech., 25(7), 1073â€“1086, 2008. </reference>
		<reference numeration="3" content_type="text"> Amediek,~A., Fix,~A., Ehret,~G., Caron,~J., and Durand,~Y.: Airborn lidar reflectance measurements at 1.57 \unit\mum in support of the A-SCOPE mission for atmospheric \chemCO_2, Atmos. Meas. Tech., 2, 755â€“772, 2009. </reference>
		<reference numeration="4" content_type="text"> Aumann,~H H., Gregorich,~D., and Gaiser,~S.: AIRS hyper-spectral measurements for climate research: Carbon dioxide and nitrous oxide effects, Geophys. Res. Lett., 32, L05806, \doi10.1029/2004GL021784, 2005. </reference>
		<reference numeration="5" content_type="text"> Baicu,~C., Caracausi,~A., Etiope,~G., and Italiano,~F.: Mud volcanoes and methane seeps in Romania: main features and gas flux, Ann. Geophys., 50(4), 501â€“511, 2007.%not found </reference>
		<reference numeration="6" content_type="text"> Barkley,~M P., FrieÃŸ,~U., and Monks,~P S.: Measuring atmospheric \chemCO_2 from space using Full Spectral Initiation (FSI) WFM-DOAS, Atmos. Chem. Phys., 6, 3517â€“3534, 2006a. </reference>
		<reference numeration="7" content_type="text"> Barkley,~M P., Monks,~P S., and Engelen,~R J.: Comparison of SCIAMACHY and AIRS \chemCO_2 measurements over North America during the summer and autumn of 2003, Geophys. Res. Lett., 33, L20805, \doi10.1029/2006GL026807, 2006b.  </reference>
		<reference numeration="8" content_type="text"> Barkley, M. P., Monks, P. S., FrieÃŸ, U., Mittermeier, R. L., Fast, H., KÃ¶rner, S., and Heimann, M.: Comparisons between SCIAMACHY atmospheric CO2 retrieved using (FSI) WFM-DOAS to ground based FTIR data and the TM3 chemistry transport model, Atmos. Chem. Phys., 6, 4483â€“4498, 2006. </reference>
		<reference numeration="9" content_type="text"> Barkley, M. P., Monks, P. S., Hewitt, A. J., Machida, T., Desai, A., Vinnichenko, N., Nakazawa, T., Yu Arshinov, M., Fedoseev, N., and Watai, T.: Assessing the near surface sensitivity of SCIAMACHY atmospheric \chemCO_2 retrieved using (FSI) WFM-DOAS, Atmos. Chem. Phys., 7, 3597â€“3619, 2007. </reference>
		<reference numeration="10" content_type="text"> Bergamaschi,~P., Frankenberg,~C., Meirink,~J F., Krol,~M., Dentener,~F., Wagner,~T., Platt,~U., Kaplan,~J O., KÃ¶rner,~S., Heimann,~M., Dlugokencky,~E J., and Goede,~A.: Satellite chartography of atmospheric methane from SCIAMACHY onboard ENVISAT: 2. Evaluation based on inverse model simulations,~J. Geophys. Res., 112, D02304, \doi10.1029/2006JD007268, 2007. </reference>
		<reference numeration="11" content_type="text"> BÃ¶sch,~H., Toon,~G C., Sen,~B., Washenfelder,~R A., Wennberg,~P O., Buchwitz,~M., de Beek,~R., Burrows,~J P., Crisp,~D., Christi,~M., Connor,~B J., Natraj,~V., and Yung,~Y L.: Space-based near-infrared \chemCO_2 measurements: testing the orbiting carbon observatory retrieval algorithm and validation concept using SCIAMACHY observations over Park Falls, Wisconsin,~J. Geophys. Res., 111, D23302, \doi10.1029/2006JD007080, 2006. </reference>
		<reference numeration="12" content_type="text"> Bovensmann,~H., Burrows,~J P., Buchwitz,~M., Frerick,~J., NoÃ«l,~S., Rozanov,~V V., Chance,~K V., and Goede,~A.: SCIAMACHY â€“ mission objectives and measurement modes,~J. Atmos. Sci., 56, 127â€“150, 1999. </reference>
		<reference numeration="13" content_type="text"> Buchwitz,~M., Rozanov,~V V., and Burrows,~J P.: A~correlated-k distribution scheme for overlapping gases suitable for retrieval of atmospheric constituents from moderate resolution radiance measurements in the visible/near-infrared spectral region,~J. Geophys. Res., 105, 15247â€“15262, 2000a. </reference>
		<reference numeration="14" content_type="text"> Buchwitz,~M., Rozanov,~V V., and Burrows,~J P.: A~near infrared optimized DOAS method for the fast global retrieval of atmospheric \chemCH_4, CO, \chemCO_2, \chemH_2O, and \chemN_2O total column amounts from SCIAMACHY/ENVISAT-1 nadir radiances,~J. Geophys. Res., 105, 15231â€“15246, 2000b. </reference>
		<reference numeration="15" content_type="text"> Buchwitz, M., de Beek, R., Burrows, J. P., Bovensmann, H., Warneke, T., Notholt, J., Meirink, J. F., Goede, A. P. H., Bergamaschi, P., Körner, S., Heimann, M., and Schulz, A.: Atmospheric methane and carbon dioxide from SCIAMACHY satellite data: initial comparison with chemistry and transport models, Atmos. Chem. Phys., 5, 941â€“962, 2005. </reference>
		<reference numeration="16" content_type="text">Buchwitz, M., de Beek, R., NoÃ«l, S., Burrows, J. P., Bovensmann, H., Bremer, H., Bergamaschi, P., KÃ¶rner, S., and Heimann, M.: Carbon monoxide, methane and carbon dioxide columns retrieved from SCIAMACHY by WFM-DOAS: year 2003 initial data set, Atmos. Chem. Phys., 5, 3313â€“3329, 2005. </reference>
		<reference numeration="17" content_type="text"> Buchwitz,~M., de Beek,~R., NoÃ«l,~S., Burrows,~J P., Bovensmann,~H., Schneising,~O., Khlystova,~I., Bruns,~M., Bremer,~H., Bergamaschi,~P., KÃ¶rner,~S., and Heimann,~M.: Atmospheric carbon gases retrieved from SCIAMACHY by WFM-DOAS: version 0.5 CO and \chemCH_4 and impact of calibration improvements on \chemCO_2 retrieval, Atmos. Chem. Phys., 6, 2727â€“2751, 2006. </reference>
		<reference numeration="18" content_type="text"> Buchwitz,~M., Schneising,~O., Burrows,~J P., Bovensmann,~H., Reuter,~M., and Nothot,~J.: First direct observation of the atmospheric \chemCO_2 year-to-year increase from space, Atmos. Chem. Phys., 7, 4249â€“4256, 2007 </reference>
		<reference numeration="19" content_type="text"> Buchwitz,~M., Reuter,~M., Schneising,~O., Heymann,~J., Bovensmann,~H., and Burrows,~J P.: Towards an improved \chemCO_2 retrieval algorithm for SCIAMACHY on ENVISAT, Proceedings Atmospheric Science Conference, Barcelona, Spain, 7â€“11 Sept 2009, ESA Special Publication SP-676, 2009. </reference>
		<reference numeration="20" content_type="text"> Burrows,~J P., HÃ¶lzle,~E., Goede,~A P H., Visser~H., and Fricke,~W.: SCIAMACHY â€“ scanning imaging absorption spectrometer for atmospheric chartography, Acta Astronaut., 35(7), 445â€“451, 1995. </reference>
		<reference numeration="21" content_type="text"> Burrows,~J P., Bovensmann,~H., Bergametti,~G., Flaud,~J M., Orphal,~J., NoÃ«l,~S., Monks,~P S., Corlett,~G K., Goede,~A P., von Clarmann,~T., Steck,~T., Fischer,~H., and Friedl-Vallon,~F.: The geostationary tropospheric pollution explorer (GeoTROPE) mission: objectives, requirements and mission concept, Adv. Space Res., 34, 682â€“687, 2004. </reference>
		<reference numeration="22" content_type="text"> Canadell,~J G., Le QuÃ©rÃ©,~C., Raupach,~M R., Field,~C B., Buitenhuis,~E T., Ciais,~P., Conway,~T J., Gillett,~N P., Houghton,~R A., and Marland,~G.: Contributions to accelerating atmospheric \chemCO_2 growth from economic activity, carbon intensity, and efficiency of natural sinks, Proceedings of the National Academy of Sciences (PNAS) of the United States of America, November 20, 2007, 104, 18866â€“18870, 2007. </reference>
		<reference numeration="23" content_type="text"> ChÃ©din,~A., Hollingsworth,~A., Scott,~N A., Serrar,~S., Crevoisier,~C., and Armante,~R.: Annual and seasonal variations of atmospheric \chemCO_2, \chemN_2O and CO concentrations retrieved from NOAA/TOVS satellite observations, Geophys. Res. Lett., 29, 1269, \doi10.1029/2001GL014082, 2002. </reference>
		<reference numeration="24" content_type="text"> ChÃ©din,~A., Serrar,~S., Scott,~N A., Crevoisier,~C., and Armante,~R.: First global measurement of midtropospheric \chemCO_2 from NOAA polar satellites: Tropical zone,~J. Geophys. Res., 108, 4581, \doi10.1029/2003JD003439, 2003. </reference>
		<reference numeration="25" content_type="text"> Chevallier,~F., Engelen,~R J., and Peylin,~P.: The contribution of AIRS data to the estimation of \chemCO_2 sources and sinks,~G. Res. Lett., 32, 23801, \doi10.1029/2005GL024229, 2005. </reference>
		<reference numeration="26" content_type="text"> Chevallier,~F., BrÃ©on,~F.-M., and Rayner,~P J.: Contribution of the orbiting carbon observatory to the estimation of \chemCO_2 sources and sinks: theoretical study in a~variational data assimilation framework,~J. Geophys. Res., 112, D09307, \doi10.1029/2006JD007375, 2007. </reference>
		<reference numeration="27" content_type="text"> Crevoisier,~C., ChÃ©din,~A., Matsueda,~H., Machida,~T., Armante,~R., and Scott,~N A.: First year of upper tropospheric integrated content of \chemCO_2 from IASI hyperspectral infrared observations, Atmos. Chem. Phys., 9, 4797â€“4810, 2009. </reference>
		<reference numeration="28" content_type="text"> Crevoisier,~C., Nobileau,~D., Fiore,~A M., Armante,~R., ChÃ©din,~A., Scott,~N A.: Tropospheric methane in the tropics â€“ first year from IASI hyperspectral infrared observations, Atmos. Chem. Phys., 9, 6337â€“6350, 2009. </reference>
		<reference numeration="29" content_type="text"> Crisp,~D., Atlas,~R M., BrÃ©on,~F.-M., Brown,~L R., Burrows,~J P., Ciais,~P., Connor,~B J., Doney,~S C., Fung,~I Y., Jacob,~D J., Miller,~C E., O&apos;Brien,~D., Pawson,~S., Randerson,~J T., Rayner,~P., Salawitch,~R S., Sander,~S P., Sen,~B., Stephens,~G L., Tans,~P P., Toon,~G C., Wennberg,~P O., Wofsy,~S C., Yung,~Y L., Kuang,~Z., Chudasama,~B., Sprague,~G., Weiss,~P., Pollock,~R., Kenyon,~D., and Schroll,~S.: The Orbiting Carbon Observatory (OCO) mission, Adv. Space Res., 34, 700â€“709, 2004. </reference>
		<reference numeration="30" content_type="text"> Crisp, D., Miller, C., Breon, F.M., Boesch, H., et al.: The Need for Atmospheric Carbon Dioxide Measurements from Space: Contributions from a~Rapid Reflight of the Orbiting Carbon Observatory, http://www.nasa.gov/pdf/363474main_OCO_Reflight.pdf, p 54, 12 May 2009. </reference>
		<reference numeration="31" content_type="text"> Christi,~M J. and Stephens,~G L.: Retrieving profiles of atmospheric \chemCO_2 in clear sky and in the presence of thin cloud using spectroscopy from the near and thermal infrared: a~preliminary case study,~J. Geophys. Res., 109, D04316, \doi10.1029/2003JD004058, 2004. </reference>
		<reference numeration="32" content_type="text"> Dimitrov,~L.: Contribution to atmospheric methane by natural seepages on the Bulgarian continental shelf, Cont. Shelf Res., 22, 2429â€“2442, 2002. </reference>
		<reference numeration="33" content_type="text"> Department of Energy and Environmental Protection Agency: Carbon Dioxide Emissions from the Generation of Electric Power in the United States, Washington, DC 20585 (DoE) and 20460 (EPA), July 2000, p 19, 2000. </reference>
		<reference numeration="34" content_type="text"> Engelen,~R J. and Stephens,~G L.: Information content of infrared satellite sounding measurements with respect to \chemCO_2,~J. Appl. Meteorol., 43, 373â€“378, 2004, </reference>
		<reference numeration="35" content_type="text"> Engelen,~R J., Andersson,~E., Chevallier,~F., Hollingsworth,~A., Matricardi,~M., McNally,~A P., ThÃ©paut,~J.-N., and Watts,~P D.: Estimating atmospheric \chemCO_2 from advanced infrared satellite radiances within an operational 4-D-Var data assimilation system: Methodology and first results,~J. Geophys. Res., 109, D19309, \doi10.1029/2004JD004777, 2004. </reference>
		<reference numeration="36" content_type="text"> Engelen,~R J. and McNally,~A P.: Estimating atmospheric \chemCO_2 from advanced infrared satellite radiances within an operational 4-D-Var data assimilation system: Results and validation,~J. Geophys. Res., 109, D18305, \doi10.1029/2005JD005982, 2005. </reference>
		<reference numeration="37" content_type="text"> Etiope,~G.: Natural emissions of methane from geological seepage in Europe, Atmos. Environ., 43, \doi10.1016/j.atmosenv.2008.03.014, 1430â€“1443, 2009. </reference>
		<reference numeration="38" content_type="text"> Etiope,~G., Feyzullayev,~A., and Baicu,~C L.: Terrestrial methane seeps and mud volcanoes: a~global perspective of gas origin, Mar. Petrol. Geol., 26, \doi10.1016/j.marpetgeo.2008.03.001 , 333â€“344, 2009. </reference>
		<reference numeration="39" content_type="text"> Frankenberg,~C., Meirink,~J F., van Weele,~M., Platt,~U., and Wagner,~T.: Assessing methane emissions from global spaceborne observations, Science, 308, 1010â€“1014, 2005. </reference>
		<reference numeration="40" content_type="text"> Frankenberg,~C., Bergamaschi,~P., Butz,~A., Houweling,~S., Meirink,~J F., Notholt,~J., Petersen,~A K., Schrijver,~H., Warneke,~T., and Aben,~I.: Tropical methane emissions: a~revised view from SCIAMACHY onboard ENVISAT, Geophys. Res. Lett., 35, L15811, \doi10.1029/2008GL034300, 2008. </reference>
		<reference numeration="41" content_type="text"> Frey,~R A., Ackerman,~S A., Liu,~Y H., Strabala,~K I., Zhang,~H., Key,~J R., and Wang,~X G.: Cloud detection with MODIS. Part I: improvements in the MODIS cloud mask for collection 5, J. Atmos. Ocean. Tech., 25(7), 1057â€“1072, 2008.  </reference>
		<reference numeration="42" content_type="text"> Gerilowski, K., Tretner, A., Krings, T., Buchwitz, M., Bertagnolio, P. P., Belemezov, F., Erzinger, J., Burrows, J. P., and Bovensmann, H.: MAMAP â€“ A new spectrometer system for column-averaged methane and carbon dioxide observations from aircraft: Instrument description and initial performance assessment, in preparation, 2010.  </reference>
		<reference numeration="43" content_type="text"> Gloudemans,~A M S., Schrijver,~H., Kleipool,~Q., van den Broek,~M M P., Straume,~A G., Lichtenberg,~G., van Hees,~R M., Aben,~I., and Meirink,~J F.: The impact of SCIAMACHY near-infrared instrument calibration on \chemCH_4 and CO total columns, Atmos. Chem. Phys., 5, 2369â€“2383, 2005. </reference>
		<reference numeration="44" content_type="text"> Greeg,~J S., Andres,~R J., and Marland,~G.: China: emissions pattern of the world leader in \chemCO_2 emissions from fossil fuel consumptions and cement production, Geophys. Res. Lett., 35, L08806, \doi10.1029/2007GJ032887, 1â€“5, 2008. </reference>
		<reference numeration="45" content_type="text"> Hamazaki,~T., Kaneko,~Y., and Kuze,~A.: Carbon dioxide monitoring from the GOSAT satellite, Proceedings XXth ISPRS conference, Istanbul, Turkey, 12â€“23 July 2004, p 3, http://www.isprs.org/congresses/istanbul2004/comm7/papers/43.pdf, 2004. </reference>
		<reference numeration="46" content_type="text"> Houweling,~S., Breon,~F.-M., Aben,~I., RÃ¶denbeck,~C., Gloor,~M., Heimann,~M., and Ciais,~P.: Inverse modeling of \chemCO_2 sources and sinks using satellite data: a~synthetic inter-comparison of measurement techniques and their performance as a~function of space and time, Atmos. Chem. Phys., 4, 523â€“538, 2004. </reference>
		<reference numeration="47" content_type="text"> Houweling,~S., Hartmann,~W., Aben,~I., Schrijver,~H., Skidmore,~J., Roelofs,~G.-J., and Breon,~F.-M.: Evidence of systematic errors in SCIAMACHY-observed \chemCO_2 due to aerosols, Atmos. Chem. Phys., 5, 3003â€“3013, 2005. </reference>
		<reference numeration="48" content_type="text"> Solomon,~S., Qin,~D., Manning,~M., Chen,~Z., Marquis,~M., Averyt,~K B., Tignor,~M., and Miller,~H L. (eds.): Climate Change 2007: The Physical Science Basis, Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC), Cambridge University Press, 996~pp., 2007. </reference>
		<reference numeration="49" content_type="text"> Jagovkina,~S V., Karol,~I L., Zubov,~V A., Lagun,~V E., Reshetnikov,~A I., and Rozanov,~E V.: Reconstruction of the methane fluxes from the West Siberian gas fields by the 3-D regional chemical tranprt model, Atmos. Environ., 34, 5319â€“5329, 2000. </reference>
		<reference numeration="50" content_type="text"> Kourtidis,~K., Kioutsioukis,~I., McGinnis,~D F., and Rapsomanikis,~S.: Effects of methane outgassing on the Black Sea atmosphere, Atmos. Chem. Phys., 6, 5173â€“5182, 2006.  </reference>
		<reference numeration="51" content_type="text"> Krings, T., Buchwitz, M., Gerilowski, K., et al.: MAMAP â€“ A new spectrometer system for column-averaged methane and carbon dioxide observations from aircraft: Retrieval algorithm and first inversions for point source emission rates, in preparation, 2010.  </reference>
		<reference numeration="52" content_type="text"> Kuang,~Z., Margolis,~J., Toon,~G., Crisp,~D., and Yung,~Y.: Spaceborne measurements of atmospheric \chemCO_2 by high-resolution NIR spectrometry of reflected sunlight: an introductory study, Geophys. Res. Lett., 29, 1716, \doi10.1029/2001GL014298, 2002. </reference>
		<reference numeration="53" content_type="text"> Leifer,~I., Roberts,~D., Margolis,~J., and Kinnaman,~F.: In situ sensing of methane emissions from natural marine hydrocarbon seeps: A~potential remote sensing technology, Earth Planet. Sc. Lett., 245, 509â€“522, 2006a. </reference>
		<reference numeration="54" content_type="text"> Leifer,~I., Luyendyk,~B P., Boles,~J., and Clark,~J F.: Natural methane seepage blowout: contribution to atmospheric methane, Global Biogeochem. Cy., 20, GB3008, \doi10.1029/2005GB002668, 1â€“9, 2006b. </reference>
		<reference numeration="55" content_type="text"> Leliveld,~J., LechtenbÃ¶hmer,~S., Assonov,~S S., Brenninkmeijer,~C A M., Dienst,~C., Fischedick,~M., and Hanke,~T.: Low methane leakage from gas pipelines, Nature, 434, 841â€“842, 2005. </reference>
		<reference numeration="56" content_type="text"> Masters,~G M.: Introduction to Environmental Engineering and Science, Prentice-Hall, Inc., 2nd edn., 413 pp., 1998. </reference>
		<reference numeration="57" content_type="text"> Meirink,~J F., Eskes,~H J., and Goede,~A P H.: Sensitivity analysis of methane emissions derived from SCIAMACHY observations through inverse modelling, Atmos. Chem. Phys., 6, 1275â€“1292, 2006. </reference>
		<reference numeration="58" content_type="text"> Meirink,~J F., Bergamaschi,~P., and Krol,~M C.: Four-dimensional variational data assimilation for inverse modelling of atmospheric methane emissions: method and comparison with synthesis inversion, Atmos. Chem. Phys., 8, 6341â€“6353, 2008. </reference>
		<reference numeration="59" content_type="text"> Miller,~C E., Crisp,~D., DeCola,~P L., Olsen,~S C., Randerson,~J T., Michalak,~A M., Alkhaled,~A., Rayner,~P., Jacob,~D J., Suntharalingam,~P., Jones,~D B A., Denning,~A S., Nicholls,~M E., Doney,~S C., Pawson,~S., Boesch,~H., Connor,~B J., Fung,~I Y., O&apos;Brien,~D O., Salawitch,~R J., Sander,~S P., Sen,~B., Tans,~P., Toon,~G C., Wennberg,~P O., Wofsy,~S C., Yung,~Y L., and Law,~R M.: Precision requirements for space-based $X_\chemCO_2$ data,~J. Geophys. Res., 112, D10314, \doi10.1029/2006JD007659, 2007. </reference>
		<reference numeration="60" content_type="text"> Palmer,~P I. and Rayner,~P.: Atmospheric science: failure to launch, Nature Geosci., 2, 247, \doi10.1038/ngeo495, 2009. </reference>
		<reference numeration="61" content_type="text"> Rayner,~P J. and O&apos;Brien,~D M.: The utility of remotely sensed \chemCO_2 concentration data in surface inversions, Geophys. Res. Lett., 28, 175â€“178, 2001. </reference>
		<reference numeration="62" content_type="text"> Rehder,~G., Keir,~R S., Suess,~E., and Pohlmann,~T.: The multiple sources and patterns of methane in North Sea water, Aquat. Geochem., 4, 403â€“427, 1998. </reference>
		<reference numeration="63" content_type="text"> Reuter,~M., Buchwitz,~M., Schneising,~O., Heymann,~J., Bovensmann,~H., and Burrows,~J P.: A~method for improved SCIAMACHY \chemCO_2 retrieval in the presence of optically thin clouds, Atmos. Meas. Tech. Discuss., 2, 2483â€“2538, 2009. </reference>
		<reference numeration="64" content_type="text"> Rodgers,~C D.: Inverse Methods for Atmospheric Sounding: Theory and Practice, World Scientific Publishing, 2000. </reference>
		<reference numeration="65" content_type="text"> Rodgers,~C D. and Connor,~B J.: Intercomparison of remote sounding instruments, J. Geophys. Res., 108(D3), 2003. </reference>
		<reference numeration="66" content_type="text"> Rozanov,~V V., Buchwitz,~M., Eichmann,~K.-U., de Beek,~R., and Burrows,~J P.: SCIATRAN â€“ a~new radiative transfer model for geophysical applications in the 240â€“2400 nm spectral region: the pseudo-spherical version, Adv. Space Res., 29, 1831â€“1835, 2002. </reference>
		<reference numeration="67" content_type="text"> Schneising, O., Buchwitz, M., Burrows, J. P., Bovensmann, H., Reuter, M., Notholt, J., Macatangay, R., and Warneke, T.: Three years of greenhouse gas column-averaged dry air mole fractions retrieved from satellite â€“ Part 1: Carbon dioxide, Atmos. Chem. Phys., 8, 3827â€“3853, 2008. %Schneising,~O., Buchwitz,~M., Burrows,~J P. et al.: Three years of greenhouse gas column-averaged %dry air mole fractions retrieved from satellite â€“ Part 1: Carbon dioxide, Atmos. Chem. Phys., 8, %3827â€“3853, 2008. </reference>
		<reference numeration="68" content_type="text"> Schneising, O., Buchwitz, M., Burrows, J. P., Bovensmann, H., Bergamaschi, P., and Peters, W.: Three years of greenhouse gas column-averaged dry air mole fractions retrieved from satellite â€“ Part 2: Methane, Atmos. Chem. Phys., 9, 443â€“465, 2009. %Schneising,~O., Buchwitz,~M., Burrows,~J P., Bovensmann,~H., Bergamaschi,~P., and Peters,~W.: %Three years of greenhouse gas column-averaged dry air mole fractions retrieved from satellite â€“ %Part 2: Methane, Atmos. Chem. Phys., 9, 443â€“465, 2009. </reference>
		<reference numeration="69" content_type="text"> Shindell,~D T. and Faluvegi,~G.: The net climate impact of coal-fired power plant emissions, Atmos. Chem. Phys. Discuss., 9, 21257â€“21284, 2009. </reference>
		<reference numeration="70" content_type="text"> Shakhova,~N E., Sergienko,~V I., and Semiletov,~I P.: The contribution of the East Siberian Shelf to the Modern Methane Cyle, Herald of the Russian Academy of Sciences, ISSN 1019â€“3316, Vol 79, No 3, 237â€“246, 2009. </reference>
		<reference numeration="71" content_type="text"> Solomon,~E A., Kastner,~M., MacDonald,~I R., and Leifer,~I.: Considerable methane fluxes to the atmosphere from hydrocarbon seeps in the Gulf of Mexico, Nature Geosci., 2, \doi10.1038/NGEO574, 561â€“563, 2009. </reference>
		<reference numeration="72" content_type="text"> Spinetti,~C., CarrÃ©re,~V., Buongiorno,~M F., Sutton,~A J., and Elias,~T.: Carbon dioxide of Pu`u`O`o volcanic plume at Kliauea retrieved by AVIRS hyperspectral data, Remote Sens. Environ., 112, \doi10.1016/j.rse.2008.03.010, 3192â€“3199, 2008. </reference>
		<reference numeration="73" content_type="text"> Strow,~L L., Hannon,~S E., De-Souza Machado,~S., Motteler,~H E., and Tobin,~D C.: Validation of the atmospheric infrared sounder radiative transfer algorithm,~J. Geophys. Res., 111, D09S06, \doi10.1029/2005JD006146, 2006. </reference>
		<reference numeration="74" content_type="text"> Sutton,~O G.: A~Theory of Eddy Diffusion in the Atmosphere, Proceedings of the Royal Society of London, Series A, Containing Papers of a~Mathematical and Physical Character, The Royal Society of London, London, UK, 135(826), 143â€“165, 1932. </reference>
		<reference numeration="75" content_type="text"> Westbrook,~G K., Thatcher,~K E., Rohling,~E J. et al.: Escape of methane from the seabed along West Spitsbergen continental margin, Geophys. Res. Lett., 36, L15608, \doi10.1029/2009GL039191, 2009. </reference>
	</references>
</article>

