<?xml version="1.0" encoding="utf-8" standalone="no"?>
<!DOCTYPE article SYSTEM "http://www.atmos-meas-tech-discuss.net/inc/amtd/copernicus.dtd">
<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques Discussions</journal_title>
		<journal_url>www.atmos-meas-tech-discuss.net</journal_url>
		<eissn>1867-8610</eissn>
		<volume_number>2</volume_number>
		<issue_number>5</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/amtd-2-2347-2009</doi>
	<article_url>http://www.atmos-meas-tech-discuss.net/2/2347/2009/</article_url>
	<abstract_html>http://www.atmos-meas-tech-discuss.net/2/2347/2009/amtd-2-2347-2009.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech-discuss.net/2/2347/2009/amtd-2-2347-2009.pdf</fulltext_pdf>
	<start_page>2347</start_page>
	<end_page>2375</end_page>
	<publication_date>2009-10-02</publication_date>
	<article_title content_type="html">A low power automated MAX-DOAS instrument for the Arctic and other remote unmanned locations</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>D. Carlson</name>
		</author>
		<author numeration="2" affiliations="1">
			<name>D. Donohoue</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>U. Platt</name>
		</author>
		<author numeration="4" affiliations="1">
			<name>W. R. Simpson</name>
			<email>wrsimpson@alaska.edu</email>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Geophysical Institute and Department of Chemistry, University of Alaska Fairbanks, Fairbanks, AK  99775-6160, USA</affiliation>
		<affiliation numeration="2" content_type="html">Institut für Umweltphysik, Universität Heidelberg, Heidelberg, Germany</affiliation>
	</affiliations>
	<abstract content_type="html">Multiple Axis Differential Optical Absorption Spectrometer (MAX-DOAS) systems are inherently
very simple instruments, which have been shown to provide extremely useful information about
a wide variety of environmental parameters. In order to exploit the potential of the
technique we have developed a new field-deployable MAX-DOAS system that is automated and
uses little power (&lt;3 W). This new instrument utilizes a fully enclosed scan head
that protects all moving parts and optics from harsh environments. Instrument diagnostics,
such as tilt monitoring and frost accumulation detection and removal, are integrated into
the main data acquisition program, which then acts to remedy problems that were
discovered. This full automation and data quality checking make this instrument ideal for
long-term deployment at remote, unmanned locations around the world, such as in polar
regions or in the monitoring of trace gas emissions from volcanoes. This instrument was
recently integrated into an ice-tethered autonomous buoy and tested in Elson Lagoon, near
Barrow, Alaska to monitor halogen chemistry in the Arctic. During this investigation
differential slant column densities (dSCDs) of BrO up to 6&amp;times;10&lt;sup&gt;14&lt;/sup&gt; molecules/cm&lt;sup&gt;2&lt;/sup&gt; were observed. Typical spectral fit residual RMS optical
densities were less than 6&amp;times;10&lt;sup&gt;&amp;minus;4&lt;/sup&gt; for solar zenith angles (SZA) &lt; 80&amp;deg; and a 6-min integration time. Here we describe the design concepts and
performance of this new MAX-DOAS instrument through detailed analyses of spectral quality,
power usage, possible instrument response biases, and typical instrument operations.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Barrie,~L A., Bottenheim,~J W., Schnell,~R C., Crutzen,~P J., and Rasmussen,~R A.: Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere, Nature, 334, 138–141, 1988. </reference>
		<reference numeration="2" content_type="text"> Bobrowski,~N., Hönninger,~G., Galle,~B., and Platt,~U.: Detection of bromine monoxide in a~volcanic plume, Nature, 423, 273–276, 2003. </reference>
		<reference numeration="3" content_type="text"> Donohoue,~D., Carlson,~D., and Simpson,~W R.: Inversion of MAX-DOAS elevation profiles to boundary layer box concentrations, visibility, and heights: Application to analysis of Arctic BrO events, in preparation, 2009. </reference>
		<reference numeration="4" content_type="text"> Dobson,~G M B. and Harrison,~D N.: Measurements of the amount of ozone in the earth&apos;s atmosphere and its relation to other geophysical conditions, Proc R. Soc. London, 110, 660–693, 1926. </reference>
		<reference numeration="5" content_type="text"> Fan,~S.-M. and Jacob,~D J.: Surface ozone depletion in Arctic spring sustained by bromine reactions on aerosols, Nature, 359, 522–524, 1992. </reference>
		<reference numeration="6" content_type="text"> Frieß,~U., Wagner,~T., Pundt,~I., Pfeilsticker,~K., and Platt,~U.: Spectroscopic measurements of tropospheric Iodine oxide at Neumayer station, Antarctica, Geophys. Res. Lett., 28, 1941–1944, 2001. </reference>
		<reference numeration="7" content_type="text"> Frieß,~U., Monks,~P S., Remedios,~J J., Rozanov,~A., Sinreich,~R., Wagner,~T., and Platt,~U.: MAX-DOAS \chemO_4 measurements: A~new technique to derive information on atmospheric aerosols: 2. Modeling studies,~J. Geophys. Res., 111, D14203, doi:10.1029/2005JD006618, 2006. </reference>
		<reference numeration="8" content_type="text"> Galle,~B., Oppenheimer,~C., Geyer,~A., McGonigle,~A., Edmonds,~M., and Horrocks,~L.: A~miniaturised ultraviolet spectrometer for remote sensing of \chemSO_2 Fluxes: A~new tool for volcano surveillance, J. Volcanol. Geotherm. Res., 119, 214–254, 2003. </reference>
		<reference numeration="9" content_type="text"> Hollwedel,~J., Wenig,~M., Beirle,~S., Kraus,~S., Kühl,~S., Wilms-Grabe, ~W., Platt,~U., and Wagner,~T.: Year-to- Year Variability of Polar Tropospheric BrO as seen by GOME, Adv. Space Res., 34, 804–808, 2004. </reference>
		<reference numeration="10" content_type="text"> Hönninger,~G. and Platt,~U.: Observations of BrO and its vertical distribution during surface ozone depletion at Alert, Atmos. Env., 36, 2481–2490, 2002. </reference>
		<reference numeration="11" content_type="text"> Hönninger, G., von Friedeburg, C., and Platt, U.: Multi axis differential optical absorption spectroscopy (MAX-DOAS), Atmos. Chem. Phys., 4, 231–254, 2004. </reference>
		<reference numeration="12" content_type="text"> Horton,~K A., Williams-Jones,~G., Garbeil,~H., Elias,~T., Sutton,~A J., Mouginis-Mark,~P., Porter,~J N., and Clegg,~S.: Real-time measurement of volcanic \chemSO_2 emissions: validation of a~new UV correlation spectrometer (FLYSPEC), Bull. Volcanol., 68(4), 323–327, 2006. </reference>
		<reference numeration="13" content_type="text"> Jacobi,~H.-W., Kaleschke,~L., Richter,~A., Rozanov,~A., and Burrows,~J P.: Observation of a~fast ozone loss over frost flowers in the marginal ice zone of the Arctic Ocean,~J. Geophys. Res., 111, D15309, doi:10.1029/2005JD006715, 2006. </reference>
		<reference numeration="14" content_type="text"> Kern,~C., Trick,~S., Rippel,~B., and Platt,~U.: Applicability of light-emitting diodes as light sources for active DOAS measurements, Appl. Optics, 45, 2077–2088, 2006. </reference>
		<reference numeration="15" content_type="text"> Knepp, T. N., Bottenheim, J., Carlsen, M., Carlson, D., Donohoue, D., Friederich, G., Matrai, P. M., Netcheva, S., Perovich, D. K., Santini, R., Shepson, P. B., Simpson, W., Stehle, R., Valentic, T., Williams, C., and Wyss, P. J.: Development of an autonomous sea ice tethered buoy for the study of ocean-atmosphere-sea ice-snow pack interactions: the O-buoy, Atmos. Meas. Tech. Discuss., 2, 2087–2121, 2009.  </reference>
		<reference numeration="16" content_type="text"> Kreher,~K., Johnston,~P V., Wood,~S W., and Platt,~U.: Ground-based measurements of tropospheric and stratospheric BrO at Arrival Heights (78$\degree$ S), Antarctica, Geophys. Res. Lett., 24, 3021–3024, 1997. </reference>
		<reference numeration="17" content_type="text"> Lindberg,~S E., Brooks,~S., Lin,~C.-J., Scott,~K J., Landis,~M S., Stevens,~R K., Goodsite,~M., and Richter,~A.: Dynamic oxidation of gaseous mercury in the Arctic troposphere at polar sunrise, Environ. Sci. Technol., 36, 1245–1256, 2002. </reference>
		<reference numeration="18" content_type="text"> McConnell,~J C., Henderson,~G S., Barrie,~L., Bottenheim,~J., Niki,~H., Langford,~C H., and Templeton,~E M J.: Photochemical bromine production implicated in Arctic boundary-layer ozone depletion, Nature, 355, 150–152, 1992. </reference>
		<reference numeration="19" content_type="text"> Moffat,~A J. and Millán,~M M.: The application of optical correlation techniques to the remote sensing of \chemSO_2 plumes using skylight, Atmos. Environ., 5, 677–690, 1971. </reference>
		<reference numeration="20" content_type="text"> Mount,~G H.: The measurement of tropospheric OH by long path absorption. 1. Instrumentation,~J. Geophys. Res., 97, 2427–2444, 1992. </reference>
		<reference numeration="21" content_type="text"> Platt,~U.: Differential optical absorption spectroscopy (DOAS), in: Air Monitoring by Spectroscopic Techniques, Chem. Anal. Ser., edited by: Sigrist,~M W., 127, 27–84, John Wiley, New York, 1994. </reference>
		<reference numeration="22" content_type="text"> Platt,~U. and Stutz,~J.: Differential Optical Absorption spectroscopy, Principles and Applications, Springer, XV, p 597, 272 illus., 29 in color. (Physics of Earth and Space Environments), ISBN 978-3-540-21193-8, 2008. </reference>
		<reference numeration="23" content_type="text"> Richter,~A., Wittrock,~F., Eisinger,~M., and Burrows,~J P.: GOME Observations of Tropospheric BrO in Northern Hemispheric Spring and Summer 1997, Geophys. Res. Lett., 25, 2683–2686, 1998. </reference>
		<reference numeration="24" content_type="text"> Schroeder,~W H., Anlauf,~K G., Barrie,~L A., Lu,~J Y., Steffen,~A., Schneeberger,~D R., and Berg,~T.: Arctic springtime depletion of mercury, Nature, 394, 331–332, 1998. </reference>
		<reference numeration="25" content_type="text"> Simpson, W. R., von Glasow, R., Riedel, K., Anderson, P., Ariya, P., Bottenheim, J., Burrows, J., Carpenter, L. J., Frieß, U., Goodsite, M. E., Heard, D., Hutterli, M., Jacobi, H.-W., Kaleschke, L., Neff, B., Plane, J., Platt, U., Richter, A., Roscoe, H., Sander, R., Shepson, P., Sodeau, J., Steffen, A., Wagner, T., and Wolff, E.: Halogens and their role in polar boundary-layer ozone depletion, Atmos. Chem. Phys., 7, 4375–4418, 2007a. </reference>
		<reference numeration="26" content_type="text"> Simpson, W. R., Carlson, D., Hönninger, G., Douglas, T. A., Sturm, M., Perovich, D., and Platt, U.: First-year sea-ice contact predicts bromine monoxide (BrO) levels at Barrow, Alaska better than potential frost flower contact, Atmos. Chem. Phys., 7, 621–627, 2007. </reference>
		<reference numeration="27" content_type="text"> Tang,~T. and McConnell,~J C.: Autocatalytic release of bromine from Arctic snow pack during polar sunrise, Geophys. Res. Lett., 23, 2633–2636, 1996. </reference>
		<reference numeration="28" content_type="text"> Tuckermann,~M., Ackermann,~R., Golz,~C., Lorenzen-Schmidt,~H., Senne,~T., Stutz,~J., Trost,~B., Unold,~W., and Platt,~U.: DOAS-observation of halogen radical-catalysed arctic boundary layer ozone destruction during the ARCTOC campaigns 1995 and 1996 in Ny-Ålesund, Spitsbergen, Tellus, 49B, 533–555, 1997. </reference>
		<reference numeration="29" content_type="text"> von Glasow, R., von Kuhlmann, R., Lawrence, M. G., Platt, U., and Crutzen, P. J.: Impact of reactive bromine chemistry in the troposphere, Atmos. Chem. Phys., 4, 2481–2497, 2004. </reference>
		<reference numeration="30" content_type="text"> Wagner,~T. and Platt,~U.: Satellite mapping of enhanced BrO concentrations in the troposphere, Nature, 395, 486–490, 1998. </reference>
		<reference numeration="31" content_type="text"> Wagner,~T., Leue,~C., Wenig,~M., Pfeilsticker,~K., and Platt,~U.: Spatial and temporal distribution of enhanced boundary layer BrO concentrations measured by the GOME instruments aboard ERS-2,~J. Geophys. Res., 106, 24225–24235, 2001. </reference>
		<reference numeration="32" content_type="text"> Wagner,~T., Dix,~B., v. Friedeburg,~C., Frieß,~U., Sanghavi,~S., Sinreich,~R., and Platt,~U.: MAX-DOAS \chemO_4 measurements: A~new technique to derive information on atmospheric aerosols – Principles and Information content,~J. Geophys. Res., 109, D22205, doi:10.1029/2004JD004904, 2004. </reference>
		<reference numeration="33" content_type="text"> Wagner, T., Ibrahim, O., Sinreich, R., Frieß, U., von Glasow, R., and Platt, U.: Enhanced tropospheric BrO over Antarctic sea ice in mid winter observed by MAX-DOAS on board the research vessel Polarstern, Atmos. Chem. Phys., 7, 3129–3142, 2007. </reference>
		<reference numeration="34" content_type="text"> Wittrock,~F., Müller,~R., Richter,~A., Bovensmann,~H., and Burrows,~J P.: Observations of Iodine monoxide above Spitsbergen, Geophys. Res. Lett., 27(10), 1471–1474, 2000. </reference>
	</references>
</article>

