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<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques Discussions</journal_title>
		<journal_url>www.atmos-meas-tech-discuss.net</journal_url>
		<eissn>1867-8610</eissn>
		<volume_number>2</volume_number>
		<issue_number>5</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/amtd-2-2191-2009</doi>
	<article_url>http://www.atmos-meas-tech-discuss.net/2/2191/2009/</article_url>
	<abstract_html>http://www.atmos-meas-tech-discuss.net/2/2191/2009/amtd-2-2191-2009.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech-discuss.net/2/2191/2009/amtd-2-2191-2009.pdf</fulltext_pdf>
	<start_page>2191</start_page>
	<end_page>2215</end_page>
	<publication_date>2009-09-24</publication_date>
	<article_title content_type="html">A comparison of spectrophotometric and denuder based approaches for the determination of gaseous molecular iodine</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>R. J. Chance</name>
			<email>rjc508@york.ac.uk</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>M. Shaw</name>
		</author>
		<author numeration="3" affiliations="1,2">
			<name>L. Telgmann</name>
		</author>
		<author numeration="4" affiliations="3">
			<name>M. Baxter</name>
		</author>
		<author numeration="5" affiliations="1">
			<name>L. J. Carpenter</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Department of Chemistry, University of York, York, YO10 5DD, UK</affiliation>
		<affiliation numeration="2" content_type="html">Department of Chemistry, University of Münster, Münster, 48149, Germany</affiliation>
		<affiliation numeration="3" content_type="html">The Food and Environment Research Agency, Sand Hutton, York, YO41 1LZ, UK</affiliation>
	</affiliations>
	<abstract content_type="html">The presence of molecular iodine in the atmosphere is thought to have implications for both
      climate and human nutritional health, but measurement of the gas at low concentrations
      requires technically demanding techniques that are not widely accessible. Here, starch
      coated denuder tubes and solvent traps coupled with spectrophotometric detection are
      evaluated and compared as relatively cheap and straightforward methods to measure gaseous
      molecular iodine at environmentally relevant concentrations. Denuder tubes were found to
      give unacceptably low and highly variable recoveries of molecular iodine from a test gas
      source, with values ranging from 1 to 62%. Blank concentrations were also high, being
      equivalent to a gas phase concentration of 5 pptv under typical operating
      conditions. Ethanol and hexane solvent traps gave much better performance. Optimisation of
      the hexane solvent trap method gave 100% recovery and an atmospheric limit of detection
      of 70 pptv, which is within the range of concentrations observed in the coastal
      marine atmosphere.</abstract>
	<references>
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</article>

