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<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques Discussions</journal_title>
		<journal_url>www.atmos-meas-tech-discuss.net</journal_url>
		<eissn>1867-8610</eissn>
		<volume_number>2</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/amtd-2-153-2009</doi>
	<article_url>http://www.atmos-meas-tech-discuss.net/2/153/2009/</article_url>
	<abstract_html>http://www.atmos-meas-tech-discuss.net/2/153/2009/amtd-2-153-2009.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech-discuss.net/2/153/2009/amtd-2-153-2009.pdf</fulltext_pdf>
	<start_page>153</start_page>
	<end_page>179</end_page>
	<publication_date>2009-01-30</publication_date>
	<article_title content_type="html">A new thermal gradient ice nucleation diffusion chamber instrument: design, development and first results using Saharan mineral dust</article_title>
	<authors>
		<author numeration="1" affiliations="1,2">
			<name>G. Kulkarni</name>
		</author>
		<author numeration="2" affiliations="1">
			<name>S. Dobbie</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>J. McQuaid</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">School of Earth and Environment, University of Leeds, Leeds, UK</affiliation>
		<affiliation numeration="2" content_type="html">now at: Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland, WA, USA</affiliation>
	</affiliations>
	<abstract content_type="html">A new Thermal Gradient ice nucleation Diffusion Chamber (TGDC) capable of
investigating ice nucleation efficiency of atmospherically important
aerosols, termed Ice Nuclei (IN), has been designed, constructed and
validated. The TGDC can produce a range of supersaturations with respect to
ice (SS&lt;sub&gt;&lt;i&gt;i&lt;/i&gt;&lt;/sub&gt;) over the temperature range of &amp;minus;10 to &amp;minus;34&amp;deg;C for
sufficiently long time needed to observe the ice nucleation by the aerosol
particles. The novel aspect of this new TGDC is that the chamber is run in
static mode with aerosol particles supported on a Teflon substrate, which
can be raised and lowered in a controlled way through the SS&lt;sub&gt;&lt;i&gt;i&lt;/i&gt;&lt;/sub&gt; profile
within the chamber, and nucleation events are directly observed using
digital photography. The TGDC consists of two ice coated plates to which a
thermal gradient is applied to produce the range of SS&lt;sub&gt;&lt;i&gt;i&lt;/i&gt;&lt;/sub&gt;. The design of
the TGDC gives the ability to understand time-related ice nucleation event
information and to perform experiments at different temperatures and SS&lt;sub&gt;&lt;i&gt;i&lt;/i&gt;&lt;/sub&gt;
conditions for different IN without changing the thermal gradient within
the TGDC. The temperature and SS&lt;sub&gt;&lt;i&gt;i&lt;/i&gt;&lt;/sub&gt; conditions of the experimental system
are validated by observing (NH&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt; deliquescence and the
results are in good agreement with the literature data. First results are
presented of the onset ice nucleation for mineral dust sampled from the
Saharan Desert, including images of nucleation and statistical distributions
of onset ice nucleation SS&lt;sub&gt;&lt;i&gt;i&lt;/i&gt;&lt;/sub&gt; as a function of temperature. This paper
illustrates how useful this new TGDC is for process level studies of ice
nucleation and more experimental investigations are needed to better
quantify the role of ice formation in the atmosphere.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Bailey, M. and Hallett, J.: Nucleation effects on the habit of vapour grown ice crystals from &amp;minus;18 to &amp;minus;42&amp;deg;C, Q. J. Roy. Meteor. Soc., 128, 1461–1483, 2002. </reference>
		<reference numeration="2" content_type="text"> Baker, M. B.: Cloud microphysics and climate, Science, 276, 1072–1078, 1997. </reference>
		<reference numeration="3" content_type="text"> Braban, C. F., Cziczo, D. J., and Abbatt, J. P. D.: Deliquescence of ammonium sulfate particles at sub-eutectic temperatures, Geophys. Res. Lett., 28(20), 3879–3882, 2001. </reference>
		<reference numeration="4" content_type="text"> Cziczo, D. J. and Abbatt, J. P. D.: Deliquescence, efflorescence and supercooling of ammonium sulfate aerosols at low temperature: implications for cirrus cloud formation and aerosol phase in the atmosphere, J. Geophys. Res., 104(D11), 13781–13790, 1999. </reference>
		<reference numeration="5" content_type="text"> DeMott, P. J., Sassen, K., Poellot, M. R., Baumgardner, D., Rogers, D. C., Brooks, S. D., Prenni, A. J., and Kreidenweis, S. M.: African dust aerosols as atmospheric ice nuclei, Geophys. Res. Lett., 30(14), 1732, doi:1029/2003GL017410, 2003. </reference>
		<reference numeration="6" content_type="text"> Flatau, P. J., Walko, R. L., and Cotton, W. R.: Polynomial fits to Saturation Vapor Pressure, J. Appl. Meteorol., 31, 1507–1513, 1992. </reference>
		<reference numeration="7" content_type="text"> Incropera, F. P., Dewitt, D. P., Bergman, T. L., and Lavine, A. S.: Introduction to Heat Transfer, 5th Ed., Wiley Publications, New York, 2007. </reference>
		<reference numeration="8" content_type="text"> Kanji, Z. A. and Abbatt, J. P. D.: Laboratory studies of ice formation via deposition mode nucleation onto mineral dust and n-hexane soot samples, J. Geophys. Res., 111, D16204, doi:10.1029/2005JD006766, 2006. </reference>
		<reference numeration="9" content_type="text"> Knopf, D. A. and Koop, T.: Heterogeneous nucleation of ice on surrogates of mineral dust, J. Geophys. Res.,111, D12201, doi:10.1029/2005JD006894, 2006. </reference>
		<reference numeration="10" content_type="text"> Lau, K. M. and Wu, H. T.: Warm rain processes over tropical oceans and climate implications, Geophys. Res. Lett., 30(24), 2290, doi:10.1029/2003GL018567, 2003. </reference>
		<reference numeration="11" content_type="text"> Mason, B. J. and Maybank, J.: Ice nucleating properties of some natural mineral dusts, Q. J. Roy. Meteor. Soc., 84, 235–241, 1958. </reference>
		<reference numeration="12" content_type="text"> Möhler, O., Field, P. R., Connolly, P., Benz, S., Saathoff, H., Schnaiter, M., Wagner, R., Cotton, R., Krämer, M., Mangold, A., and Heymsfield, A. J.: Efficiency of the deposition mode ice nucleation on mineral dust particles, Atmos. Chem. Phys., 6, 3007–3021, 2006. </reference>
		<reference numeration="13" content_type="text"> Onasch, T., Siefert, R., Brooks, S., Prenni, A., Murray, B., Wilson, M., and Tolbert, M.: Infrared spectroscopic study of the deliquescence and efflorescence of ammonium sulfate aerosol as a function of temperature, J. Geophys. Res., 104(D17), 21317–21326, 1999. </reference>
		<reference numeration="14" content_type="text"> Pruppacher, H. R. and Klett, J. D.: Microphysics of Clouds and Precipitation, Springer Publications, New York, 1997. </reference>
		<reference numeration="15" content_type="text"> Roberts, P. and Hallett, J.: A laboratory study of the ice nucleation properties of some mineral particulates, Q. J. Roy. Meteor. Soc., 94, 25–34, 1967. </reference>
		<reference numeration="16" content_type="text"> Rogers, D. C.: Development of a continuous flow thermal gradient diffusion chamber for ice nucleation studies, Atmos. Res., 22, 149–181, 1988. </reference>
		<reference numeration="17" content_type="text"> Rogers, R. R. and Yau, M. K.: A Short Course in Cloud Physics, Pergamon Press, New York, 1989. </reference>
		<reference numeration="18" content_type="text"> Salam, A., Lohmann, U., Crenna, B., Lesins, G., Klages, P., Rogers, D., Irani, R., MacGillivray, A. and Coffin, M.: Ice nucleation studies of mineral dust particles with a new continuous flow diffusion chamber, Aerosol Sci. Tech., 40(2), 134–143, 2006. </reference>
		<reference numeration="19" content_type="text"> Schaller, R. C. and Fukuta, N.: Ice nucleation by aerosol particles: Experimental studies using a wedge-shaped ice thermal diffusion chamber, J. Atmos. Sci., 36, 1788–1802, 1979. </reference>
		<reference numeration="20" content_type="text"> Stetzer, O., Baschek, B., Lüönd, F., and Lohmann, U.: The Zurich Ice Nucleation Chamber (ZINC) - A New Instrument to Investigate Atmospheric Ice Formation, Aerosol Sci. Tech., 42(1), 64–74, 2008. </reference>
		<reference numeration="21" content_type="text"> Turnbull, D.: Kinetics of heterogeneous nucleation, J. Chem. Phys., 18, 198–203, 1950. </reference>
		<reference numeration="22" content_type="text"> Twomey, S.: Pollution and planetary albedo, Atmos. Environ., 8(12), 1251–1256, 1974. </reference>
		<reference numeration="23" content_type="text"> Vali, G.: Nucleation Terminology, Bull. Am. Meteorol. Soc., 66, 1426–1427, 1985. </reference>
	</references>
</article>

