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<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques Discussions</journal_title>
		<journal_url>www.atmos-meas-tech-discuss.net</journal_url>
		<eissn>1867-8610</eissn>
		<volume_number>2</volume_number>
		<issue_number>3</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/amtd-2-1351-2009</doi>
	<article_url>http://www.atmos-meas-tech-discuss.net/2/1351/2009/</article_url>
	<abstract_html>http://www.atmos-meas-tech-discuss.net/2/1351/2009/amtd-2-1351-2009.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech-discuss.net/2/1351/2009/amtd-2-1351-2009.pdf</fulltext_pdf>
	<start_page>1351</start_page>
	<end_page>1382</end_page>
	<publication_date>2009-06-03</publication_date>
	<article_title content_type="html">A laboratory flow reactor with gas particle separation and on-line MS/MS for product identification in atmospherically important reactions</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>J. F. Bennett</name>
		</author>
		<author numeration="2" affiliations="1,2">
			<name>F. Collin</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>D. R. Hastie</name>
			<email>hastie@yorku.ca</email>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Department of Chemistry and Centre for Atmospheric Chemistry, York University, 4700 Keele St., Toronto, Ontario, M3J 1P3, Canada</affiliation>
		<affiliation numeration="2" content_type="html">now at: Université Paris Descartes – CNRS UMR 8601, Paris, France</affiliation>
	</affiliations>
	<abstract content_type="html">A system to study the gas and particle phase products from gas phase
hydrocarbon oxidation is described. It consists of a gas phase photochemical
flow reactor followed by a diffusion membrane denuder to remove gases from
the reacted products, or a filter to remove the particles. Chemical analysis
is performed by an atmospheric pressure chemical ionization (APCI) triple
quadrupole mass spectrometer. A diffusion membrane denuder is shown to
remove trace gases to below detectable limits so the particle phase can be
studied. The system was tested by examining the products of the oxidation of
m-xylene initiated by HO radicals. Dimethylphenol was observed in both the
gas and particle phases although individual isomers could not be identified.
Two furanone isomers, 5-methyl-2(3H)furanone and 3-methyl-2(5H)furanone were
identified in the particulate phase, but the isobaric product 2,5 furandione
was not observed. One isomer of dimethyl-nitrophenol was identified in the
particle phase but not in the gas phase.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Allan, J. D., Jimenez, J. L., Williams, P. I., Alfarra, M. R., Bower, K. N., Jayne, J. T., Coe, H., and Worsnop, D. R.: Quantitative sampling using an aerodyne aerosol mass spectrometer: 1. techniques of data interpretation and error analysis, J. Geophys. Res.-Atmos., 108, 4090, doi:10.1029/2003JD001607, 2003. </reference>
		<reference numeration="2" content_type="text"> Andino, J. M., Smith, J. N., Flagan, R. C., Goddard III, W. A., and Seinfeld, J. H.: Mechanism of atmospheric photooxidation of aromatics: A theoretical study, J. Phys. Chem., 100, 10967–10980, 1996. </reference>
		<reference numeration="3" content_type="text"> Aschmann, S. M., Atkinson, R., and Arey, J.: Products of reaction of OH radicals with alpha-pinene, J. Geophys. Res.-Atmos., 107, 4191, doi:10.1029/2001JD001098, 2002. </reference>
		<reference numeration="4" content_type="text"> Atkinson, R.: Kinetics and Mechanisms of the Gas-Phase Reactions of the Hydroxyl Radical with Organic Compounds, Journal of physical and chemical reference data. Monograph; no. 1, Published by the American Chemical Society and the American Institute of Physics for the National Institute of Standards and Technology, New York, USA, 1989. </reference>
		<reference numeration="5" content_type="text"> Bernstein, J. A., Alexis, N., Barnes, C., Bernstein, I. L., Bernstein, J. A., Nel, A., Peden, D., Diaz-Sanchez, D., Tarlo, S. M., and Williams, P. B.: Health effects of air pollution, J. Allergy Clin. Immun., 114, 1116–1123, 2004. </reference>
		<reference numeration="6" content_type="text"> Chiappini, L., Perraudin, E., Durand-Jolibois, R., and Doussin, J. F.: Development of a supercritical fluid extraction-gas chromatography-mass spectrometry method for the identification of highly polar compounds in secondary organic aerosols formed from biogenic hydrocarbons in smog chamber experiments, Anal. Bioanal. Chem., 386, 1749–1759, 2006. </reference>
		<reference numeration="7" content_type="text"> Claeys, M., Szmigielski, R., Kourtchev, I., Van der Veken, P., Vermeylen, R., Maenhaut, W., Jaoui, M., Kleindienst, T. E., Lewandowski, M., Offenberg, J. H., and Edney, E. O.: Hydroxydicarboxylic acids: Markers for secondary organic aerosol from the photooxidation of α-pinene, Environ. Sci. Technol., 41, 1628–1634, 2007. </reference>
		<reference numeration="8" content_type="text"> Dawson, P. H., French, J. B., Buckley, J. A., Douglas, D. J., and Simmons, D.: The use of triple quadrupoles for sequential mass spectrometry: 2-A detailed case study, Org. Mass Spectrom., 17, 212–219, 1982. </reference>
		<reference numeration="9" content_type="text"> Ding, Y. M., Pang, Y. B., Eatough, D. J., Eatough, N. L., and Tanner, R. L.: High-volume diffusion denuder sampler for the routine monitoring of fine particulate matter: II. field evaluation of the PC-BOSS, Aerosol Sci. Tech., 36, 383–396, 2002. </reference>
		<reference numeration="10" content_type="text"> Dockery, D., Pope, C. A., Xu, X., Spengler, J., Ware, J., Fay, M., Ferris, B., and Speizer, F.: An association between air pollution and mortality in six U.S. cities, N. Engl. J. Med., 329, 1753–1759, 1993. </reference>
		<reference numeration="11" content_type="text"> Drewnick, F., Hings, S. S., DeCarlo, P., Jayne, J. T., Gonin, M., Fuhrer, K., Weimer, S., Jimenez, J. L., Demerjian, K. L., Borrmann, S., and Worsnop, D. R.: A new time-of-flight aerosol mass spectrometer (TOF-AMS) - instrument description and first field deployment, Aerosol Sci. Tech., 39, 637–658, 2005. </reference>
		<reference numeration="12" content_type="text"> Forstner, H. J. L., Flagan, R. C., and Seinfeld, J. H.: Secondary organic aerosol from the photooxidation of aromatic hydrocarbons: Molecular composition, Environ. Sci. Technol., 31, 1345–1358, 1997. </reference>
		<reference numeration="13" content_type="text"> Gard, E., Mayer, J. E., Morrical, B. D., Dienes, T., Fergenson, D. P., and Prather, K. A.: Real-time analysis of individual atmospheric aerosol particles: Design and performance of a portable ATOFMS, Anal. Chem., 69, 4083–4091, 1997. </reference>
		<reference numeration="14" content_type="text"> Good, A., Durden, D. A., and Kebarle, P.: Mechanism and rate constants of ion-molecule reactions leading to formation of H$^+$(H&lt;sub&gt;2&lt;/sub&gt;O)$_n$ in moist oxygen and air, J. Chem. Phys., 52, 222–229, 1970a. </reference>
		<reference numeration="15" content_type="text"> Good, A., Durden, D. A., and Kebarle, P.: Ion-molecule reactions in pure nitrogen and nitrogen containing traces of water at total pressures 0.5–4 torr kinetics of clustering reactions forming H$^+$(H&lt;sub&gt;2&lt;/sub&gt;O)$_n$, J. Chem. Phys., 52, 212–221, 1970b. </reference>
		<reference numeration="16" content_type="text"> Hamilton, J., Webb, P., Lewis, A., and Reviejo, M.: Quantifying small molecules in secondary organic aerosol formed during the photo-oxidation of toluene with hydroxyl radicals, Atmos. Environ., 39, 7263–7275, 2005. </reference>
		<reference numeration="17" content_type="text"> Hansel, A., Jordan, A., Holzinger, R., Prazeller, P., Vogel, W., and Lindinger, W.: Proton transfer reaction mass spectrometry: Online trace gas analysis at the ppb level, Int. J. Mass Spectrom., 149/150, 609–619, 1995. </reference>
		<reference numeration="18" content_type="text"> Hearn, J. D. and Smith, G. D.: A chemical ionization mass spectrometry method for the online analysis of organic aerosols, Anal. Chem., 76, 2820–2826, 2004. </reference>
		<reference numeration="19" content_type="text"> Hinds, W. C.: Aerosol Technology: Properties, Behavior, and Measurement of Airborne Particles, 2nd, Wiley, New York, USA, 1999. </reference>
		<reference numeration="20" content_type="text"> Hoffmann, T., Bandur, R., Hoffmann, S., and Warscheid, B.: On-line characterization of gaseous and particulate organic analytes using atmospheric pressure chemical ionization mass spectrometry, Spectrochim. Acta B, 57B, 1635–1647, 2002. </reference>
		<reference numeration="21" content_type="text"> Jaoui, M. and Kamens, R. M.: Mass balance of gaseous and particulate products from β-Pinene/O&lt;sub&gt;3&lt;/sub&gt;/Air in the absence of light and β-Pinene/NO&lt;sub&gt;x&lt;/sub&gt;/Air in the presence of natural sunlight, J. Atmos. Chem., 45, 101–141, 2003. </reference>
		<reference numeration="22" content_type="text"> Krewski, D., Burnett, R. T., Goldberg, M. S., Hoover, K., Siemiatycki, J., Abrahamowicz, M., and White, W. H.: Validation of the harvard six cities study of particulate air pollution and mortality, N. Engl. J. Med., 350, 198–199, 2004. </reference>
		<reference numeration="23" content_type="text"> Kroll, J. H. and Seinfeld, J. H.: Chemistry of secondary organic aerosol: Formation and evolution of low-volatility organics in the atmosphere, Atmos. Environ., 42, 3593–3624, 2008. </reference>
		<reference numeration="24" content_type="text"> Larsen, B. R., DiBella, D., Glasius, M., Winterhalter, R., Jensen, N. R., and Hjorth, J.: Gas-phase OH oxidation of monoterpenes: Gaseous and particulate products, J. Atmos. Chem., 38, 231–276, 2001. </reference>
		<reference numeration="25" content_type="text"> Librando, V. and Tringali, G.: Atmospheric fate of OH initiated oxidation of terpenes. reaction mechanism of α-pinene degradation and secondary organic aerosol formation, J. Environ. Manage., 75, 275–282, 2005. </reference>
		<reference numeration="26" content_type="text"> May, K. R.: The collison nebulizer: Description, performance and application, J. Aerosol Sci., 4, 235–243, 1973. </reference>
		<reference numeration="27" content_type="text"> Noyes, W. A.: n-butyl nitrite, Organic Syntheses, 16, 7–8, 1936. </reference>
		<reference numeration="28" content_type="text"> Pöschl, U.: Atmospheric aerosols: Composition, transformation, climate and health effects, Angew. Chem.-Int. Edit., 44, 7520–7540, 2005. </reference>
		<reference numeration="29" content_type="text"> Pratt, K. A., Mayer, J. E., Holecek, J. C., Moffet, R. C., Sanchez, R. O., Rebotier, T. P., Furutani, H., Gonin, M., Fuhrer, K., Su, Y., Guazzotti, S., and Prather, K. A.: Development and characterization of an aircraft aerosol time-of-flight mass spectrometer, Anal. Chem., 81, 1792–1800, 2009. </reference>
		<reference numeration="30" content_type="text"> Ruiz, P. A., Lawrence, J. E., Ferguson, S. T., Wolfson, J. M., and Koutrakis, P.: A counter-current parallel-plate membrane denuder for the non-specific removal of trace gases, Environ. Sci. Technol., 40, 5058–5063, 2006. </reference>
		<reference numeration="31" content_type="text"> Soderholm, S. C.: Analysis of diffusion battery data, J. Aerosol Sci., 10, 163–175, 1979. </reference>
		<reference numeration="32" content_type="text"> Tanimoto, H., Aoki, N., Inomata, S., Hirokawa, J., and Sadanaga, Y.: Development of a PTR-TOFMS instrument for real-time measurements of volatile organic compounds in air, Int. J. Mass Spectrom., 263, 1–11, 2007. </reference>
		<reference numeration="33" content_type="text"> Temime, B., Healy, R. M., and Wenger, J. C.: A denuder-filter sampling technique for the detection of gas and particle phase carhonyl compounds, Environ. Sci. Technol., 41, 6514–6520, 2007. </reference>
		<reference numeration="34" content_type="text"> Thomson, D. S., Schein, M. E., and Murphy, D. M.: Particle analysis by laser mass spectrometry WB-57F instrument overview, Aerosol Sci. Technol., 33, 153–169, 2000. </reference>
		<reference numeration="35" content_type="text"> Warscheid, B., Kuckelmann, U., and Hoffmann, T.: Direct quantitative analysis of organic compounds in the gas and particle phase using a modified atmospheric pressure chemical ionization source in combination with ion trap mass spectrometry, Anal. Chem., 75, 1410–1417, 2003. </reference>
		<reference numeration="36" content_type="text"> Zhang, Y.: Indoor Air Quality Engineering, CRC Press, Boca Raton, Fla, 2005. </reference>
	</references>
</article>

