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<article language="en">
	<journal>
		<journal_title>Atmospheric Measurement Techniques Discussions</journal_title>
		<journal_url>www.atmos-meas-tech-discuss.net</journal_url>
		<eissn>1867-8610</eissn>
		<volume_number>1</volume_number>
		<issue_number>1</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/amtd-1-281-2008</doi>
	<article_url>http://www.atmos-meas-tech-discuss.net/1/281/2008/</article_url>
	<abstract_html>http://www.atmos-meas-tech-discuss.net/1/281/2008/amtd-1-281-2008.html</abstract_html>
	<fulltext_pdf>http://www.atmos-meas-tech-discuss.net/1/281/2008/amtd-1-281-2008.pdf</fulltext_pdf>
	<start_page>281</start_page>
	<end_page>320</end_page>
	<publication_date>2008-11-28</publication_date>
	<article_title content_type="html">Methodology and calibration for continuous measurements of biogeochemical trace gas and O&lt;sub&gt;2&lt;/sub&gt; concentrations from a 300-m tall tower in central Siberia</article_title>
	<authors>
		<author numeration="1" affiliations="1,3">
			<name>E. A. Kozlova</name>
			<email>e.kozlova@uea.ac.uk</email>
		</author>
		<author numeration="2" affiliations="3">
			<name>A. C. Manning</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>Y. Kisilyakhov</name>
		</author>
		<author numeration="4" affiliations="1">
			<name>T. Seifert</name>
		</author>
		<author numeration="5" affiliations="1">
			<name>M. Heimann</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Max Planck Institute for Biogeochemistry, Jena, Germany</affiliation>
		<affiliation numeration="2" content_type="html">V. N. Sukachev Institute of Forest SB RAS, Krasnoyarsk, Russia</affiliation>
		<affiliation numeration="3" content_type="html">University of East Anglia, School of Environmental Sciences, Norwich, UK</affiliation>
	</affiliations>
	<abstract content_type="html">We present an integrated system for measuring atmospheric
concentrations of CO&lt;sub&gt;2&lt;/sub&gt;, O&lt;sub&gt;2&lt;/sub&gt;, CH&lt;sub&gt;4&lt;/sub&gt;, CO, and N&lt;sub&gt;2&lt;/sub&gt;O in central
Siberia. Our project aims to demonstrate the feasibility of establishing
long-term, continuous, high precision atmospheric measurements to elucidate
greenhouse gas processes from a very remote mid-continental boreal
environment. Air is sampled from five heights on a custom-built 300-m tower.
Common features to all species&apos; measurements include air intakes, an air
drying system, flushing procedures, and data processing methods. Calibration
standards are shared among all five measured species as a result of
extending and optimising a proven methodology for long-term O&lt;sub&gt;2&lt;/sub&gt;
calibration. Our system achieves the precision and accuracy requirements
specified by the European Union&apos;s &quot;CarboEurope&quot; and &quot;ICOS&quot; (Integrated
Carbon Observing System) programmes in the case of CO&lt;sub&gt;2&lt;/sub&gt;, O&lt;sub&gt;2&lt;/sub&gt;, and
CH&lt;sub&gt;4&lt;/sub&gt;, while CO and N&lt;sub&gt;2&lt;/sub&gt;O require some further improvements. We found
that it is not possible to achieve these high precision measurements without
skilled technical assistance on-site, primarily because of 2–3 month delays
in access to data and diagnostic information. We present results on the
stability of reference standards in high pressure cylinders. We also found
that some previous methods do not mitigate fractionation of O&lt;sub&gt;2&lt;/sub&gt; in a
sample airstream to a satisfactory level.</abstract>
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</article>

